The 22-year-old defender spent the latter part of last season at Vicenza, and he is set for another term in Italy's second tier after joining Sassuolo.
The Neroverdi began their first-ever Serie B campaign with a loss against Salernitana, who also won promotion after finishing first in Serie C1/B last season (Sassuolo topped Serie C1/A).
Andreolli, who is part of the Azzurrini squad for their upcoming European Championship qualifiers, is expected to feature against Pisa next weekend.
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